A method that conducts epoxidation of allylic alcohols. Tolerates a wider array of functional groups. A method that conducts epoxidation of alkenes. It is dissimilar to Katsuki-Sharpless asymmetric epoxidation by showing high selectivity towards simple alkenes without coordinated substituents.
We possess technologies using manganese catalysts and titanium catalysts. This catalyst holds an activity level twenty folds of that of TEMPO and enables the oxidation of secondary alcohols with large steric hindrance, which was difficult in TEMPO note that this oxidation catalyst can be supplied in bulk. It is possible to use safely compared to Dess-Martin reagent and IBX reagent, since its reaction proceeds according to the catalytic amount and active species are generated in situ note that this oxidation catalyst can be supplied in bulk.
However, remote access to EBSCO's databases from non-subscribing institutions is not allowed if the purpose of the use is for commercial gain through cost reduction or avoidance for a non-subscribing institution. Convert currency. Imprint: Academic Press. Publication date Note Includes index. Excellent Customer Service. Journal of the American Chemical Society , 49 , Your email.
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History History. Organization Organization. Network Network. Citations PDF 87 KB. Abstract The Sharpless epoxidation reaction is considered one of the most powerful advances in asymmetric organic synthesis 1. Cited By. This article is cited by 14 publications. Barry M.
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